A Universal Strategy for Hollow Metal Oxide Nanoparticles Encapsulated into B/N Co-Doped Graphitic Nanotubes as High-Performance Lithium-Ion Battery Anodes

Abstract

Yolk–shell nanostructures have received great attention for boosting the performance of lithium-ion batteries because of their obvious advantages in solving the problems associated with large volume change, low conductivity, and short diffusion path for Li⁺ ion transport. A universal strategy for making hollow transition metal oxide (TMO) nanoparticles (NPs) encapsulated into B, N co-doped graphitic nanotubes (TMO@BNG (TMO = CoO, Ni₂O₃, Mn₃O₄) through combining pyrolysis with an oxidation method is reported herein. The as-made TMO@BNG exhibits the TMO-dependent lithium-ion storage ability, in which CoO@BNG nanotubes exhibit highest lithium-ion storage capacity of 1554 mA h g⁻¹ at the current density of 96 mA g⁻¹, good rate ability (410 mA h g⁻¹ at 1.75 A g⁻¹), and high stability (almost 96% storage capacity retention after 480 cycles). The present work highlights the importance of introducing hollow TMO NPs with thin wall into BNG with large surface area for boosting LIBs in the terms of storage capacity, rate capability, and cycling stability.

A universal protocol is demonstrated for the encapsulation of hollow MO (MO = CoO, Ni₂O₃, Mn₃O₄) nanoparticles into B and N co-doped graphitic nanotubes for high-capacity long-life lithium-ion battery anodes.

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