Improved Efficiency and Stability of Perovskite Solar Cells Induced by CO Functionalized Hydrophobic Ammonium-Based Additives

Abstract

Because of the rapid rise of the efficiency, perovskite solar cells are currently considered as the most promising next-generation photovoltaic technology. Much effort has been made to improve the efficiency and stability of perovskite solar cells. Here, it is demonstrated that the addition of a novel organic cation of 2-(6-bromo-1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)ethan-1-ammonium iodide (2-NAM), which has strong Lewis acid and base interaction (between CO and Pb) with perovskite, can effectively increase crystalline grain size and reduce charge carrier recombination of the double cation FA_0.83MA_0.17PbI_2.51Br_0.49 perovskite film, thus boosting the efficiency from 17.1 ± 0.8% to 18.6 ± 0.9% for the 0.1 cm² cell and from 15.5 ± 0.5% to 16.5 ± 0.6% for the 1.0 cm² cell. The champion cell shows efficiencies of 20.0% and 17.6% with active areas of 0.1 and 1.0 cm², respectively. Moreover, the hysteresis behavior is suppressed and the stability is improved. The result provides a promising route to further elevate efficiency and stability of perovskite solar cells by the fine tuning of triple organic cations.

A new organic additive (2-NAM) is introduced into the perovskite film. The introduction of this additive boosts the efficiency from 17.1 ± 0.8% to 18.6 ± 0.9% for the 0.1 cm² area cells and from 15.5 ± 0.5% to 16.5 ± 0.6% for the 1.0 cm² area cells. Moreover, the hydrophobic nature of this additive effectively reduces the influence from moisture, thus enhancing the solar cell stability.

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