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Παρασκευή 8 Σεπτεμβρίου 2017

Liquid Quinones for Solvent-Free Redox Flow Batteries

Liquid benzoquinone and naphthoquinone having diethylene glycol monomethyl ether groups are designed and synthesized as redox active materials that dissolve supporting electrolytes. The Li-ion batteries based on the liquid quinones using LiBF4/PC show good performance in terms of voltage, capacity, energy efficiency, and cyclability in both static and flow modes. A battery is constructed without using intentionally added organic solvent, and its high energy density (264 W h L−1) demonstrates the potential of solvent-free organic redox flow batteries using liquid active materials.

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Liquid benzoquinone and naphthoquinone having diethylene glycol monomethyl ether groups are designed and synthesized as redox active materials that dissolve supporting electrolytes. A battery is constructed without using intentionally added organic solvent, and its high energy density (264 W h L−1) demonstrates the potential of organic redox flow batteries using liquid active materials.



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