Roll-to-Roll Production of Layer-Controlled Molybdenum Disulfide: A Platform for 2D Semiconductor-Based Industrial Applications

Abstract

A facile methodology for the large-scale production of layer-controlled MoS₂ layers on an inexpensive substrate involving a simple coating of single source precursor with subsequent roll-to-roll-based thermal decomposition is developed. The resulting 50 cm long MoS₂ layers synthesized on Ni foils possess excellent long-range uniformity and optimum stoichiometry. Moreover, this methodology is promising because it enables simple control of the number of MoS₂ layers by simply adjusting the concentration of (NH₄)₂MoS₄. Additionally, the capability of the MoS₂ for practical applications in electronic/optoelectronic devices and catalysts for hydrogen evolution reaction is verified. The MoS₂-based field effect transistors exhibit unipolar n-channel transistor behavior with electron mobility of 0.6 cm² V⁻¹ s⁻¹ and an on-off ratio of ≈10³. The MoS₂-based visible-light photodetectors are fabricated in order to evaluate their photoelectrical properties, obtaining an 100% yield for active devices with significant photocurrents and extracted photoresponsivity of ≈22 mA W⁻¹. Moreover, the MoS₂ layers on Ni foils exhibit applicable catalytic activity with observed overpotential of ≈165 mV and a Tafel slope of 133 mV dec⁻¹. Based on these results, it is envisaged that the cost-effective methodology will trigger actual industrial applications, as well as novel research related to 2D semiconductor-based multifaceted applications.

A facile methodology for the large-scale production of layer-controlled MoS₂ layers on an inexpensive substrate implemented with subsequent two-step roll-to-roll-based thermal decomposition is developed. The resulting 50 cm long MoS₂ layers synthesized on Ni foils possess excellent long-range uniformity. This methodology is a promising way for simple control of the number of MoS₂ layers by adjusting the concentration of (NH₄)₂MoS₄.

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